cis-Bis(1,10-phenanthroline-κ2 N,N′)bis(thiocyanato-κN)magnesium(II)
نویسندگان
چکیده
The title compound, [Mg(NCS)(2)(C(12)H(8)N(2))(2)], has been synthesized from the hydro-thermal reaction of MgCl(2), KSCN, 1,10-phenanthroline and H(2)O. Its structure is isotypic with the Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) analogues. The Mg(II) cation has a slightly distorted octa-hedral geometry containing four N atoms from two 1,10-phenanthroline mol-ecules and two N atoms from two thio-cyanate anions. The asymmetric unit contains one-half mol-ecule, and the complete complex has 2 symmetry.
منابع مشابه
[2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN 2)-1,10-phenanthroline-κ2 N,N′]bis(thiocyanato-κN)cadmium(II)
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